翻訳と辞書 Words near each other ・ Methylprednisolone aceponate ・ Methylpyridinium ・ Methylquercetagetin 6-O-methyltransferase ・ Methylquercetin ・ Methylrhenium trioxide ・ Methylscopolamine bromide ・ Methylselenocysteine ・ Methylserotonin ・ Methylsilane ・ Methylsterol monooxygenase ・ Methylsulfonylmethane ・ Methyltestosterone ・ Methyltetrahydroprotoberberine 14-monooxygenase ・ Methylthioadenosine nucleosidase ・ Methylthioirontricarbonyl dimer ・ Methylthiomethyl ether ・ Methylthioribulose 1-phosphate dehydratase ・ Methylthiouracil ・ Methyltransferase ・ Methyltransferase 2 ・ Methyltrichlorosilane ・ Methyltrimethoxysilane ・ Methyltyramine ・ Methylumbelliferone ・ Methylumbelliferyl-acetate deacetylase ・ Methylvanillylecgonine ・ Methyphobia ・ Methyprylon ・ Methysergide ・ Methysia Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Methylthiomethyl ether ： ウィキペディア英語版 Methylthiomethyl ether In organic chemistry a methylthiomethyl (MTM) ether is a protective group for hydroxyl groups. Hydroxyl groups are present in many chemical compounds and they must be protected during oxidation, acylation, halogenation, dehydration and other reactions to which they are susceptible. Many kinds of protective groups for hydroxyl groups have been developed and used in organic chemistry, but the number of protective groups for tertiary hydroxyl groups, which are susceptible to acid-catalyzed dehydration, is still small because of their poor reactiveness. They can be easily protected with MTM ethers and recovered in good yield. To introduce an MTM ether to a hydroxyl group, two methods are mainly used. One is a typical Williamson ether synthesis using an MTM halide as an MTM resource and sodium hydride (NaH) as a base. The other is a special method, in which dimethyl sulfoxide (DMSO) and acetic anhydride (Ac2O) are used. In this case, the reaction proceeds with Pummerer rearrangement: MTM ethers have another advantage. They are removed by neutral (but toxic) mercuric chloride, to which most other ethers are stable. As a result, the selective deprotection of polyfunctional molecules becomes possible using MTM ethers as the protective groups for their hydroxyl groups. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Methylthiomethyl ether」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.